Thin film synthesis and violet-light emission of widegap Cu<sub>2</sub>ZnI<sub>4</sub>

نویسندگان

چکیده

Cu2ZnI4 (CZI) is a non-perovskite-type iodide that has zincblende-derived layered structure. Since the identification of CZI in late 1980s, thin film synthesis and optoelectronic properties this compound have not ever been reported. We expect to be potential material because several Cu-based halides are excellent semiconductors. In study, we synthesized films investigated their optical properties. Single-phase polycrystalline were obtained for first time using vacuum evaporation. These highly transparent visible region, absorption analysis revealed widegap with bandgap 3.1 eV. Furthermore, exhibited violet-light photoluminescence originating from excitonic transitions even at room temperature. Our findings suggest candidate light-emitting material.

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ژورنال

عنوان ژورنال: Journal of the Ceramic Society of Japan

سال: 2022

ISSN: ['1882-0743', '1348-6535']

DOI: https://doi.org/10.2109/jcersj2.21169